Preliminary Studies of Surface Structure and Dynamics of Rutile TiO2(110) Using Helium Atom Scattering.

E. A. AKHADOV, J. BROCK, T. W. TRELENBERG, AND J. G. SKOFRONICK , D. H. VAN WINKLE (Physics Department and MARTECH), S. A. SAFRON (Chemistry Department and MARTECH), Florida State University, Tallahassee, FL 32306; F. FLAHERTY, Valdosta State University, Valdosta, GA 31698,

Helium atom scattering is employed to study surface structure and dynamics of the rutile TiO2(110) single crystal. The surface preparation method followed established techniques1. Structure in both high symmetry [1-10] and [001] directions was investigated and results agree with earlier STM studies1. The specularly reflected signal was observed by varying the beam wave vector from 6 Å-1 to 11 Å-1. This provides information on step-height evolution on the surface and demonstrates how substrate temperature affects that evolution. Surface dynamics measurements were performed in [1-10] and [001] directions. Two dispersionless modes, one around 7 meV and another around 1-2 meV, and other features of surface vibrations were observed.

*Supported by U. S. Department of Energy Grant Number DE-FGO2-97ER45635.

1U. Diebold et al, Surface Science 411 (1998) 137-153