TITLE:

ES&H Manual

 

DOCUMENT ID:

3510 Appendix T5

Response to Chemical Spills[1]

 

 

Jefferson Lab has determined that working with chemicals carries an unmitigated Risk Code >2. At a minimum all tasks requiring chemicals are discussed with the supervisor prior to commencement of work. An Operational Safety Procedure (OSP) is written for work considered to be Risk Code >2 in accordance with ES&H Manual Chapter 3210 Work Planning, Control, and Authorization Process.

 

1.0            Purpose

 

Jefferson Lab considers spills to be a hazard. This procedure provides minimum action steps and contact information to ensure prompt, safe clean-up of a chemical spill. 

 

The process steps satisfy applicable federal, state, and local requirements as outlined in ES&H Manual Chapter 2410 Appendix T1 Hazard Issues List.

 

2.0            Scope

 

Only those who are trained are authorized to clean-up a spill involving hazardous material. It is recognized that listing the requirements for every chemical used at Jefferson Lab would be prohibitive, it is therefore required that qualified chemical workers read and follow the requirements/recommendation for spill clean-up listed on a chemical’s safety data sheet (SDS).  

 

This appendix is written in coordination with ES&H Manual 3510 Emergency Response Activities and ES&H Manual 6610 Chemical Hygiene Program.

 

3.0            Responsibilities

NOTE:           Management authority may be delegated at the discretion of the responsible manager.

 

3.1              Anyone at Jefferson Lab:

·         If you see or produce a chemical spill contact:

o   Security at 269-5822, or

o   Request assistance from the Hazardous Waste Coordinator at 269-7882.

 

3.2              Hazardous Waste Coordinator

·         Provide chemical waste disposal assistance.

 

4.0            Process Steps

 

If there is personal over-exposure to a chemical, follow the process steps outlined in ES&H Manual Chapter 6610 Appendix T6 Response to Chemical Over-Exposure.

 

Unless otherwise stated anyone at Jefferson Lab may perform the following process steps.

 

4.1              Spills

 

Step 1:             Note the material, location, and quantity.

 

Step 2:             Protect yourself and others

 

IF

Spill is

THEN

Outdoors

Evacuate (~100ft) upwind.

Indoors

Evacuate the room and close all doors and windows.

 

 

Step 3:             Call Security (269-5822) immediately and give the following information:

o   Identity of the material,

o   Location of the spill,

o   Approximate quantity,

o   Other hazards or emergency conditions (traffic or personnel concerns) as requested.

 

Step 4:             Contain the Release (if safe to do so):

o   Block drains to prevent seepage into the sewer or storm system (this includes indoor plumbing and outdoor storm systems).  

o   Construct a barrier around the spill using spill pads, socks, from an appropriate spill kit, or other compatible material as available (e.g.: soil) to prevent spreading and to minimize damage.

 

Step 5:             Wait and/or direct responders to the spill. 

 

4.2              Waste Clean-up and Disposal

 

Contact the Hazardous Waste Coordinator (269-7882) to remove waste and other suspect material left after completion of clean-up procedure(s).

 

5.0            Revision Summary

 

Revision 3.0 – 02/01/16 – Periodic Review; formerly 3510-T6; deleted content related to activities requiring training or work control documents

Revision 2.1  11/17/14 – Deleted note box added to 4.2 Waste Disposal per last revision; clarified instructions to Contain the Release of small drips/non-hazardous spills and large spills noted in 4.1 Chemical Spills, Step 4, per T.Menefee.

Revision 2.0 – 01/07/14 – Formerly 6610T7 Clean-up Chemical Spills Procedure; Defined small and large spills in 2.0 Scope; Added responsibilities to 3.2 Chemical Worker to read and understand OSP for specific area(s) assigned, and ensure required training is current; Specified to evacuate “upwind” in 4.1 Chemical Spills Step 2; Added “Clean-up” and note box to 4.2 Waste Disposal; per J.Williams and T.Menefee; AD-ESHQ approved.

Revision 1.2 – 06/28/13 – Triennial Review; added note of area specific WCDs

Revision 1.1 – 03/30/11 – Removed reference to the Chemical Assistance Team

Revision 1.0 – 07/05/10 – Updated to reflect current laboratory operations

 

ISSUING AUTHORITY

TECHNICAL POINT-OF-CONTACT

APPROVAL DATE

REVIEW DATE

REV.

 

 

ESH&Q Division

Tina Menefee

02/01/16

02/01/21

3.0

 

This document is controlled as an on line file.  It may be printed but the print copy is not a controlled document.  It is the user’s responsibility to ensure that the document is the same revision as the current on line file.  This copy was printed on 2/19/2016.



[1] For purposes of this appendix a “spill” is considered any quantity of chemical that an individual require assistance, or special material/equipment to remove.